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Creation of certifed reference material of ascorbic acid composition
https://doi.org/10.32446/0368-1025it.2020-4-57-65
Abstract
The article presents the application of the “one hundred minus amount of impurities” approach in the development of a reference material of ascorbic acid composition using state primary and secondary measurement standards. The method of high-performance liquid chromatography (HPLC) with a detector on a diode array is used for the quantitative content of impurities of similar structure, with the highest content compared to other impurities. Traceability of certified values was provided using the calibration method of the State primary standard of units of mass (molar) fraction and mass (molar) concentration of organic components in liquid and solid substances and materials based on liquid and gas chromatography-mass spectrometry with isotope dilution and gravimetry GET 208-2019. The paper presents the use of the reference material of ascorbic acid composition to test the qualifications of laboratories, satisfactory results of the participants confirmed the applicability of the reference material for various measurement methods
About the Authors
M. P. Krasheninina
Ural Scientifi c Research Institute for Metrology – Affi liated branch of the D. I. Mendeleyev Institute for Metrology
Russian Federation
Russian Federation
Mariya P. Krasheninina
Ekaterinburg
O. S. Shokhina
Ural Scientifi c Research Institute for Metrology – Affi liated branch of the D. I. Mendeleyev Institute for Metrology
Russian Federation
Russian Federation
Olga S. Shokhina
Ekaterinburg
A. S. Sergeeva
Ural Scientifi c Research Institute for Metrology – Affi liated branch of the D. I. Mendeleyev Institute for Metrology
Russian Federation
Russian Federation
Anna S. Sergeeva
Ekaterinburg
T. N. Tabatchikova
Ural Scientifi c Research Institute for Metrology – Affi liated branch of the D. I. Mendeleyev Institute for Metrology
Russian Federation
Russian Federation
Tatyana N. Tabatchikova
Ekaterinburg
V. B. Baranovskaya
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Russian Federation
Russian Federation
Vasilisa B. Baranovskaya
Moscow
Y. A. Karpov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Russian Federation
Russian Federation
Yuri A. Karpov
Moscow
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For citations:
Krasheninina M.P., Shokhina O.S., Sergeeva A.S., Tabatchikova T.N., Baranovskaya V.B., Karpov Y.A. Creation of certifed reference material of ascorbic acid composition. Izmeritel`naya Tekhnika. 2020;(4):57-65. (In Russ.) https://doi.org/10.32446/0368-1025it.2020-4-57-65
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