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Unifed fundamental equation of state of argon: construction technique in the framework of the scaling theory and tables of standard reference data
V. A. Kolobaev,
S. V. Rykov,
I. V. Kudryavtseva,
E. E. Ustyuzhanin,
P. V. Popov,
V. A. Rykov,
A. D. Kozlov https://doi.org/10.32446/0368-1025it.2022-11-9-16
Abstract
Method for constructing a unified fundamental equation of state is developed. This fundamental equation of state is related to the matter and woks in a wide range of state parameters. The technique is based on the Benedek hypothesis and the method of pseudocritical points, which are based on the assertion that the isochoric and isobaric heat capacities, the isothermal compressibility coefficient, and the speed of sound in the vicinity of the critical point on the critical and noncritical isochores are described by power dependences with the same critical indices. There is a number of conditions, which considered in the work and connected with fundamental equation of state: it satisfies the requirements of the scaling theory for critical phenomena; in the gas region, it transforms into a virial equation of state; it satisfactorily transmits experimental data on thermal and caloric properties in wide temperature and pressure ranges; in the near-critical region, it describes experimental data on the density, the isochoric heat capacity, the isobaric heat capacity, and the speed of sound. It is built tables of standard reference data for argon in the temperature range from 83.806 K to 1200 K and at pressures from 0.1 to 1000 MPa on the basis of the fundamental equation of state.
About the Authors
V. A. Kolobaev
Russian Research Institute of Metrological Service
Russian Federation
Russian Federation
Viktor A. Kolobaev
Moscow
S. V. Rykov
University ITMO
Russian Federation
Russian Federation
Sergey V. Rykov
St. Petersburg
I. V. Kudryavtseva
University ITMO
Russian Federation
Russian Federation
Irina V. Kudryavtseva
St. Petersburg
E. E. Ustyuzhanin
National Research University “MPE”
Russian Federation
Russian Federation
Evgeniy E. Ustyuzhanin
Moscow
P. V. Popov
Russian Research Institute of Metrological Service
Russian Federation
Russian Federation
Peter V. Popov
Moscow
V. A. Rykov
University ITMO
Russian Federation
Russian Federation
Vladimir A. Rykov
St. Petersburg
A. D. Kozlov
Russian Research Institute of Metrological Service
Russian Federation
Russian Federation
Aleksandr D. Kozlov
Moscow
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For citations:
Kolobaev V.A., Rykov S.V., Kudryavtseva I.V., Ustyuzhanin E.E., Popov P.V., Rykov V.A., Kozlov A.D. Unifed fundamental equation of state of argon: construction technique in the framework of the scaling theory and tables of standard reference data. Izmeritel`naya Tekhnika. 2022;(11):9-16. (In Russ.) https://doi.org/10.32446/0368-1025it.2022-11-9-16
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