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Thermodynamic properties of R1233zd(E) refrigerant: a technique for constructing the fundamental equation of state and tabulated data
V. A. Kolobaev,
S. V. Rykov,
I. V. Kudryavtseva,
E. E. Ustyuzhanin,
P. V. Popov,
V. A. Rykov,
A. D. Kozlov https://doi.org/10.32446/0368-1025it.2022-5-22-28
Abstract
The substance trans-1-chloro-3,3,3-trifluoro-1-propene (R1233zd(E)) refers to fl uorinated hydrocarbon compounds; it is currently being considered as an alternative, fi rstly, to the refrigerant R245fa, which works in organic Rankine cycles. Secondly, R1233zd(E) works as an alternative to the R134a and R123 refrigerants previously used in chillers. To calculate the equilibrium properties (density, entropy, etc.) of this substance, a unifi ed fundamental equation of state (UFEoS) is proposed that satisfi es a number of requirements, including: a) takes into account the asymmetric nature of the behavior of a real fl uid relative to the critical isochore in accordance with the requirements of modern physics of critical phenomena, b) implements the transition of the UFEoS into the virial equation of state in the region of a rarefi ed gas, c) in a wide vicinity of the critical point is consistent with the scaling Berestov equation. On the basis of UFEoS in the temperature range from the triple point temperature, 195.15 K to 450 K and pressures from 0.1 MPa to 100 MPa, thermodynamic tables of standard reference data in the singlephase region and on the saturation line, including density, entropy and enthalpy, speed of sound, isochoric and isobaric heat capacities and heat of vaporization are calculated. Based on GOST 34100.3-2017/ISO/IEC Guide 98-3:2008 and the international methodology recommended for assessing the uncertainty of tabulated data, the uncertainty of the properties included in these standard tables was estimated. A comparative analysis of the properties calculated by the UFEoS with the experimental and literature data on the properties of R1233zd(E) has been made.
About the Authors
V. A. Kolobaev
All-Russian Research Institute of Metrological Service
Russian Federation
Russian Federation
Viktor A. Kolobaev
Moscow
S. V. Rykov
University ITMO
Russian Federation
Russian Federation
Sergey V. Rykov
St. Petersburg
I. V. Kudryavtseva
University ITMO
Russian Federation
Russian Federation
Irina V. Kudryavtseva
St. Petersburg
E. E. Ustyuzhanin
National Research University “MPE”
Russian Federation
Russian Federation
Evgeniy E. Ustyuzhanin
Moscow
P. V. Popov
All-Russian Research Institute of Metrological Service
Russian Federation
Russian Federation
Peter V. Popov
Moscow
V. A. Rykov
University ITMO
Russian Federation
Russian Federation
Vladimir A. Rykov
St. Petersburg
A. D. Kozlov
All-Russian Research Institute of Metrological Service
Russian Federation
Russian Federation
Aleksandr D. Kozlov
Moscow
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Review
For citations:
Kolobaev V.A., Rykov S.V., Kudryavtseva I.V., Ustyuzhanin E.E., Popov P.V., Rykov V.A., Kozlov A.D. Thermodynamic properties of R1233zd(E) refrigerant: a technique for constructing the fundamental equation of state and tabulated data. Izmeritel`naya Tekhnika. 2022;(5):22-28. (In Russ.) https://doi.org/10.32446/0368-1025it.2022-5-22-28
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